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Abstract Assessing the prevalence of atmospheres on rocky planets around M-dwarf stars is a top priority of exoplanet science. High-energy activity from M dwarfs can destroy the atmospheres of these planets, which could explain the lack of atmosphere detections to date. Volcanic outgassing has been proposed as a mechanism to replenish the atmospheres of tidally heated rocky planets. L 98-59 b, a sub-Earth transiting a nearby M dwarf, was recently identified as the most promising exoplanet to detect a volcanic atmosphere. We present the transmission spectrum of L 98-59 b from four transits observed with JWST NIRSpec G395H. Although the airless model provides an adequate fit to the data based on itsχ², an SO₂atmosphere is preferred by 3.6σover a flat line in terms of the Bayesian evidence. Such an atmosphere would likely be in a steady state where volcanism balances escape. If so, L 98-59 b must experience at least eight times as much volcanism and tidal heating per unit mass as Io. If volcanism is driven by runaway melting of the mantle, we predict the existence of a subsurface magma ocean in L 98-59 b extending up toR_p ∼  60%–90%. An SO₂-rich volcanic atmosphere on L 98-59 b would be indicative of an oxidized mantle with an oxygen fugacity offO₂ > IW + 2.7, and it would imply that L 98-59 b must have retained some of its volatile endowment despite its proximity to its star. Our findings suggest that volcanism may revive secondary atmospheres on tidally heated rocky planets around M dwarfs. 

Abstract Kepler-51 is a ≲1 Gyr old Sun-like star hosting three transiting planets with radii ≈6–9R_⊕and orbital periods ≈45–130 days. Transit timing variations (TTVs) measured with past Kepler and Hubble Space Telescope (HST) observations have been successfully modeled by considering gravitational interactions between the three transiting planets, yielding low masses and low mean densities (≲0.1 g cm⁻³) for all three planets. However, the transit time of the outermost transiting planet Kepler-51d recently measured by the James Webb Space Telescope 10 yr after the Kepler observations is significantly discrepant from the prediction made by the three-planet TTV model, which we confirmed with ground-based and follow-up HST observations. We show that the departure from the three-planet model is explained by including a fourth outer planet, Kepler-51e, in the TTV model. A wide range of masses (≲M_Jup) and orbital periods (≲10 yr) are possible for Kepler-51e. Nevertheless, all the coplanar solutions found from our brute-force search imply masses ≲10M_⊕for the inner transiting planets. Thus, their densities remain low, though with larger uncertainties than previously estimated. Unlike other possible solutions, the one in which Kepler-51e is around the 2:1 mean motion resonance with Kepler-51d implies low orbital eccentricities (≲0.05) and comparable masses (∼5M_⊕) for all four planets, as is seen in other compact multiplanet systems. This work demonstrates the importance of long-term follow-up of TTV systems for probing longer-period planets in a system. 

Abstract The spectroscopic characterization of terrestrial exoplanets over a wide spectral range from the near- to the mid-infrared will be made possible for the first time with the JWST. One challenge is that it is not known a priori whether such planets possess optically thick atmospheres or even any atmospheres altogether. However, this challenge also presents an opportunity, the potential to detect the surface of an extrasolar world. This study explores the feasibility of characterizing with the JWST the atmosphere and surface of LHS 3844b, the highest signal-to-noise rocky thermal emission target among planets that are cool enough to have nonmolten surfaces. We model the planetary emission, including the spectral signal of both the atmosphere and surface, and we explore all scenarios that are consistent with the existing Spitzer 4.5 μ m measurement of LHS 3844b from Kreidberg et al. In summary, we find a range of plausible surfaces and atmospheres that are within 3 σ of the observationless reflective metal-rich, iron-oxidized, and basaltic compositions are allowed, and atmospheres are restricted to a maximum thickness of 1 bar, if near-infrared absorbers at ≳100 ppm are included. We further make predictions on the observability of surfaces and atmospheres and find that a small number (∼3) of eclipse observations should suffice to differentiate between surface and atmospheric features. We also perform a Bayesian retrieval analysis on simulated JWST data and find that the surface signal may make it harder to precisely constrain the abundance of atmospheric species and may falsely induce a weak H 2 O detection. 

Abstract The recent inference of sulfur dioxide (SO₂) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations^1–3suggests that photochemistry is a key process in high-temperature exoplanet atmospheres⁴. This is because of the low (<1 ppb) abundance of SO₂under thermochemical equilibrium compared with that produced from the photochemistry of H₂O and H₂S (1–10 ppm)^4–9. However, the SO₂inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 μm and, therefore, the detection of other SO₂absorption bands at different wavelengths is needed to better constrain the SO₂abundance. Here we report the detection of SO₂spectral features at 7.7 and 8.5 μm in the 5–12-μm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)¹⁰. Our observations suggest an abundance of SO₂of 0.5–25 ppm (1σrange), consistent with previous findings⁴. As well as SO₂, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 μm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1–8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range. 

Abstract Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations. 

Abstract Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems^1,2. Access to the chemical inventory of an exoplanet requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based^3–5and high-resolution ground-based^6–8facilities. Here we report the medium-resolution (R ≈ 600) transmission spectrum of an exoplanet atmosphere between 3 and 5 μm covering several absorption features for the Saturn-mass exoplanet WASP-39b (ref. ⁹), obtained with the Near Infrared Spectrograph (NIRSpec) G395H grating of JWST. Our observations achieve 1.46 times photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO₂(28.5σ) and H₂O (21.5σ), and identify SO₂as the source of absorption at 4.1 μm (4.8σ). Best-fit atmospheric models range between 3 and 10 times solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO₂, underscore the importance of characterizing the chemistry in exoplanet atmospheres and showcase NIRSpec G395H as an excellent mode for time-series observations over this critical wavelength range¹⁰. 

Abstract Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy (for example, refs.^1,2) provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution and high precision, which, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST’s Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0–4.0 micrometres, exhibit minimal systematics and reveal well defined molecular absorption features in the planet’s spectrum. Specifically, we detect gaseous water in the atmosphere and place an upper limit on the abundance of methane. The otherwise prominent carbon dioxide feature at 2.8 micrometres is largely masked by water. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1–100-times solar (that is, an enrichment of elements heavier than helium relative to the Sun) and a substellar C/O ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation (for example, refs.^3,4,) or disequilibrium processes in the upper atmosphere (for example, refs.^5,6).